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Collects Amazing Spider-Man Annual #25, Peter Parker, The Spectacular Spider-Man Annual #11, Web of Spider-Man Annual #7.
When synthetic Vibranium, created by the Roxxon corporation, may end up up in the wrong hands, it will be up to Spider-Man, Iron Man and Black Panther to stop the likes of Kingpin, Ghost, and a new player in the super-powered Sunturion. The situation escalates when Kingpin makes a deal with Ultron, who may be more powerful than the three heroes can handle if he gets control over the new synthetic Vibranium!